How to Create a Procedure Comparison Matrix for Contaminated Soils

Markus Reichenbach ·

A process comparison matrix for contaminated soils is created by first identifying all relevant remediation methods, then establishing uniform evaluation criteria, and systematically assessing each method according to technical suitability, cost, time requirements, and environmental impact. The result is a structured decision-making basis that enables planners, authorities, and clients to select a method in a transparent and comprehensible way. The following sections answer the most important questions about the structure, evaluation logic, and common mistakes when creating such a matrix.

What criteria belong in a process comparison matrix for soils?

A process comparison matrix for contaminated soils should include at minimum the criteria of technical suitability, remediation efficiency, cost, time requirements, environmental impact, legal permissibility, and reusability of the treated material. These criteria cover both the technical and the economic and regulatory dimensions of soil remediation.

Depending on the project context, additional criteria may be added. At sensitive sites, emissions during treatment play an important role. For large volumes, plant capacity is decisive. For projects with tight schedules, treatment speed moves to the foreground. A summary of typical evaluation criteria:

  • Technical suitability: Can the method effectively treat the contaminants present?
  • Remediation efficiency: Are the target values reliably and permanently achieved?
  • Cost: Treatment costs, transport, disposal of residual materials
  • Time requirements: Duration of approval, treatment, and aftercare
  • Environmental impact: Emissions, energy consumption, fate of contaminants
  • Legal permissibility: Approvability under BImSchG, KrWG, and state law
  • Recyclability of output material: Can the treated material be reused?

Each criterion should be assigned a weighting that reflects the project-specific requirements. A uniform scale, for example from 1 to 5, facilitates the subsequent comparison.

Which remediation methods are typically compared with one another?

When comparing soil treatment methods, thermal desorption, soil washing, biological in-situ and ex-situ methods, immobilization, and secure landfill disposal are generally considered. Which methods are specifically included in the matrix depends on the type of contamination, soil composition, and site conditions.

Ex-situ methods

Ex-situ methods treat the soil after excavation outside the site. These include thermal desorption, soil washing, and biological ex-situ treatment. They enable controlled treatment under defined conditions and are particularly suitable for complex or highly concentrated contaminations.

In-situ methods

In-situ methods treat the soil at the location without excavating it. Examples include biological stimulation, chemical oxidation, and thermal in-situ treatment. These methods are often more cost-effective, but their effectiveness is harder to control, and they are not always reliable for heterogeneous soils or volatile contaminants.

In addition, landfill disposal is frequently listed as a comparison option, even though it does not constitute actual remediation. It serves as a reference point for costs and residual risks.

How is thermal desorption evaluated compared to other methods?

Thermal desorption performs particularly strongly in process comparisons when it comes to complex contaminant mixtures, high contaminant concentrations, or difficult-to-degrade compounds. Contaminants such as PAHs, PCBs, PCDD/PCDF, PFAS, cyanides, or nitroaromatics are destroyed or completely driven out of the solid material during thermal treatment, something other methods often cannot achieve with the same reliability.

In the criteria comparison, thermal soil treatment shows the following strengths and limitations:

  • Remediation efficiency: Very high for organic contaminants and mercury
  • Contaminant spectrum: Broad, including difficult-to-degrade compounds such as PFAS and PCDD/PCDF
  • Output quality: The treated material is frequently recyclable
  • Cost: Higher than biological methods, but calculable and without long-term risks
  • Time requirements: Faster than biological methods, as no long incubation periods are required
  • Environmental impact: Controllable through multi-stage exhaust gas purification

Biological methods are more cost-effective, but are limited to certain contaminant classes and require significantly more time. Soil washing achieves good results with sandy soils and soluble contaminants, but reaches its limits with cohesive soils or persistent organic compounds. Landfill disposal does not eliminate contaminants but merely relocates the risk.

How is the process comparison matrix built step by step?

A process comparison matrix for contaminated soils is built in four steps: identify methods, define and weight criteria, evaluate each method per criterion, and combine the weighted scores into an overall result. This structured approach ensures transparency and comprehensibility.

  1. Select methods: All methods that are fundamentally technically suitable are listed. Unsuitable options can be excluded with a brief justification.
  2. Define and weight criteria: The evaluation criteria are established and assigned weighting factors that reflect the project objectives. Time-critical projects weight time requirements more heavily; cost-driven projects weight economic efficiency more heavily.
  3. Evaluate per criterion: Each method receives a score for each criterion on a uniform scale. The evaluation should be based on comprehensible assumptions and be documented.
  4. Calculate weighted total score: Score multiplied by weighting factor yields the weighted partial score. The sum of all partial scores yields the overall result per method.

The result shows which method performs best under the given framework conditions. The matrix does not replace a professional decision, but it makes the decision logic visible and verifiable for all parties involved.

When is a simple matrix not sufficient?

A simple process comparison matrix is not sufficient when multiple methods must be combined, when the data on contamination is incomplete, or when regulatory requirements prescribe an in-depth risk assessment. In these cases, the matrix is only one component within a more comprehensive remediation concept.

Specific situations in which an extended assessment becomes necessary:

  • Multi-phase contaminations: When both organic and inorganic contaminants are present at a site, no single method can meet all requirements. This calls for a material flow management approach that coordinates different treatment pathways.
  • Incomplete analytics: If reliable data on contaminant distribution is lacking, scores in the matrix are speculative. Further investigation measures must first be carried out.
  • Regulatory requirements: Some approval procedures require a formal remediation investigation in accordance with LABO guidelines or comparable regulatory frameworks, which goes beyond a simple matrix evaluation.
  • Very large volumes or heterogeneous materials: For projects involving hundreds of thousands of tonnes or highly variable soil composition, pilot tests and dynamic adjustments to the method selection are required.

What mistakes are commonly made when creating a process comparison matrix?

The most common mistakes when creating a process comparison matrix for contaminated soils are missing or arbitrary weightings, omitting relevant methods, insufficient documentation of evaluation assumptions, and confusing technical suitability with economic preference. These mistakes undermine the informative value of the matrix and can lead to incorrect method decisions.

The following problems occur regularly in detail:

  • Weightings without justification: If weighting factors are not derived from the project objectives, they reflect personal preferences rather than objective requirements.
  • Pre-selection too early: Methods are excluded before their suitability has been assessed. This distorts the result and can trigger queries from authorities.
  • Lack of contaminant specificity: A matrix that does not differentiate between different contaminant classes evaluates technical suitability imprecisely. Contaminant specificity is particularly critical for persistent organic compounds or mercury.
  • Cost as the sole decision criterion: Low treatment costs are of little use if the method does not reliably achieve the remediation objectives or if follow-up costs arise due to residual risks.
  • Lack of traceability: Without documentation of the evaluation assumptions, the matrix cannot be reviewed by third parties and is vulnerable in approval procedures.

How ARE Deutzen supports method selection for contaminated soils

ARE Deutzen GmbH brings more than 30 years of experience in the treatment of contaminated mineral waste and supports civil engineering companies and industrial clients in finding the right treatment option for their site. The technical expertise at the Deutzen site forms the basis for well-founded, practice-oriented method consulting.

ARE Deutzen specifically offers:

  • Thermal soil treatment in a rotary kiln at temperatures of up to approximately 600 °C, depending on the material and contaminant load, covering a broad contaminant spectrum including PAHs, PCBs, PFAS, PCDD/PCDF, cyanides, mercury, and chlorinated hydrocarbons
  • Mechanical-physical pre-treatment as a complement to thermal treatment
  • Material flow management for complex projects with various waste types and treatment pathways
  • Interim storage of contaminated material during the project duration
  • Certified waste management company under KrWG with permits under BImSchG

If you need a reliable basis for method selection for your remediation project or are looking directly for a treatment solution, contact ARE Deutzen. Contact our representatives for an expert initial assessment of your project.